中文名 | 黄芪皂苷 III |
英文名 | Astragaloside III |
别名 | 黄芪皂苷Ⅲ 黄芪皂甙III 黄芪皂苷 III 黄芪皂苷III对照品, 黄芪皂苷III(标准品) ASTRAGALOSIDE III 黄芪皂苷III 黄芪皂苷III (ASTRAGALOSIDE III) |
英文别名 | Astragaloside-Ⅲ Astragaloside III ASTRAGALOSIDE III(SH) β-D-Xylopyranoside,(3β,6α,16β,20R,24S)-20,24-epoxy-6,16,25-trihydroxy-9,19-cyclolanostan-3-yl2-O-β-D-glucopyranosyl- b-D-Xylopyranoside, (3b,6a,16b,20R,24S)-20,24-epoxy-6,16,25-trihydroxy-9,19-cyclolanostan-3-yl 2-O-b-D-glucopyranosyl- (3beta,6alpha,9beta,16beta,20R,24S)-6,16,25-Trihydroxy-20,24-epoxy-9,19-cyclolanostan-3-yl 2-O-beta-D-glucopyranosyl-beta-D-xylopyranoside beta-D-xylopyranoside, (3beta,6alpha,9beta,16beta,20R,24S)-20,24-epoxy-6,16,25-trihydroxy-9,19-cyclolanostan-3-yl 2-O-beta-D-glucopyranosyl- |
CAS | 84687-42-3 |
化学式 | C41H68O14 |
分子量 | 784.97 |
InChI | InChI=1/C41H68O14/c1-35(2)24(53-34-30(26(46)21(45)17-51-34)54-33-29(49)28(48)27(47)22(16-42)52-33)9-11-41-18-40(41)13-12-37(5)32(39(7)10-8-25(55-39)36(3,4)50)20(44)15-38(37,6)23(40)14-19(43)31(35)41/h19-34,42-50H,8-18H2,1-7H3/t19-,20-,21+,22+,23-,24-,25-,26-,27+,28-,29+,30+,31-,32-,33-,34-,37+,38-,39+,40-,41+/m0/s1 |
密度 | 1.39±0.1 g/cm3(Predicted) |
熔点 | 245~247℃ |
沸点 | 906.8±65.0 °C(Predicted) |
比旋光度 | +21.4°(c=0.83,methanol) |
闪点 | 502.2°C |
蒸汽压 | 0mmHg at 25°C |
溶解度 | 甲醇 (微溶) 、吡啶 (微溶) |
折射率 | 1.62 |
酸度系数 | 12.89±0.70(Predicted) |
存储条件 | Hygroscopic, -20°C Freezer, Under inert atmosphere |
外观 | 固体 |
颜色 | White to Off-White |
物化性质 | 白色结晶粉末,可溶于甲醇、乙醇、DMSO等有机溶剂,来源于黄芪。 |
MDL号 | MFCD28978172 |
海关编号 | 29389090 |
参考资料 展开查看 | 1. 姚维一, 王春, 龚弟鸿,等. 基于UHPLC-Q-Exactive Orbitrap-MS快速鉴定补阳还五汤及其在人血浆和尿液中药物化学成分[J]. 中国现代应用药学, 2020(14). 2. 李洋洋,张苡铭,魏孔熙,周婷,何进鹏,丁楠,周谷城,史桐凡,柯宜诚,牛帆,刘永琦,张利英.黄芪不同有效成分对电离辐射致BMSCs DNA损伤防护作用的比较研究[J].中国药房,2020,31(24):2987-2992. 3. Zhang, Yuping, et al. "Integration of magnetic solid phase fishing and off-line two-dimensional high-performance liquid chromatography–diode array detector–mass spectrometry for screening and identification of human serum albumin binders from Radix Astraga 4. Yuping Zhang, Shuyun Shi, Junfang Guo, Qingping You, Deshan Feng, On-line surface plasmon resonance-high performance liquid chromatography–tandem mass spectrometry for analysis of human serum albumin binders from Radix Astragali, Journal of Chromatography 5. [IF=7.514] Yuping Zhang et al."Integration of magnetic solid phase fishing and off-line two-dimensional high-performance liquid chromatography–diode array detector–mass spectrometry for screening and identification of human serum albumin binders from Radix Astragali 6. [IF=4.759] Yuping Zhang et al."On-line surface plasmon resonance-high performance liquid chromatography–tandem mass spectrometry for analysis of human serum albumin binders from Radix Astragali."J Chromatogr A. 2013 Jun;1293:92 7. [IF=3.882] Kunpeng Yin et al."Lanthanide Metal–Organic Framework-Based Fluorescent Sensor Arrays to Discriminate and Quantify Ingredients of Natural Medicine."Langmuir. 2021;37(17):5321–5328 |
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